Low-Temperature Oxidation of Isopropylbenzene Mediated by the System of NHPI, Fe(acac)3 and 1,10-phenanthroline | Sciact - CRIS-система Института катализа

Low-Temperature Oxidation of Isopropylbenzene Mediated by the System of NHPI, Fe(acac)3 and 1,10-phenanthroline Краткое сообщение

Журнал

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Вых. Данные

Год: 2021, Том: 149, Номер статьи : 106218, Страниц : 5 DOI: 10.1016/j.catcom.2020.106218

Ключевые слова

Oxidation; Isopropylbenzene; N-Hydroxyphthalimide; Iron(III) acetylacetonate; 1,10-Phenantroline; Isopropylbenzene hydroperoxide

Авторы

Kuznetsova N.I. ¹ , Babushkin D.E. ¹ , Zudin V.N. ¹ , Koscheeva O.S. ² , Kuznetsova L.I. ¹

Организации

1	Boreskov Institute of Catalysis SB RAS, 5 Prospekt Lavrentieva, Novosibirsk 630090, RF
2	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Prospect Lavrentueva, Novosibirsk 630090, RF

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	19-43-540008
2	Федеральное агентство научных организаций России	0303-2016-0006 (V.44.1.6)

Highly efficient oxidation of isopropylbenzene mediated by the system of NHPI/Fe(acac)3/Phen has been carried out at temperature as low as 60 °C. Significant improvement of catalysis by NHPI was associated with an enhanced oxidizing ability of Fe(III) tandem with Phen, which caused the intense generation of PINO. Furthermore, NMR observations revealed formation of a hydrogen-bonded NHPI-Phen adduct soluble in acetonitrile and isopropylbenzene. Based on this phenomenon, the system was applicable for the oxidation of solvent-free isopropylbenzene. The promise of the system of NHPI/Fe(acac)3/Phen for the selective synthesis of isopropylbenzene hydroperoxide was demonstrated by oxidation at a low content of Fe(acac)3.

Kuznetsova N.I. , Babushkin D.E. , Zudin V.N. , Koscheeva O.S. , Kuznetsova L.I.
Low-Temperature Oxidation of Isopropylbenzene Mediated by the System of NHPI, Fe(acac)3 and 1,10-phenanthroline

Catalysis Communications. 2021. V.149. 106218 :1-5. DOI: 10.1016/j.catcom.2020.106218 WOS Scopus РИНЦ OpenAlex CAPlusCA

Полный текст от издателя

Поступила в редакцию:	8 сент. 2020 г.
Принята к публикации:	30 окт. 2020 г.
Опубликована online:	5 нояб. 2020 г.
Опубликована в печати:	15 янв. 2021 г.

≡ Web of science:	WOS:000600589400031
≡ Scopus:	2-s2.0-85096119738
≡ РИНЦ:	45144522
≡ OpenAlex:	W3095393572
≡ Chemical Abstracts:	2020:2438783
≡ Chemical Abstracts (print):	174:11347

≡ Scopus	22	Сбор данных от 15.02.2026
≡ Web of science	19	Сбор данных от 20.02.2026
≡ РИНЦ	24	Сбор данных от 15.02.2026
≡ OpenAlex	25	Сбор данных от 15.02.2026