Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond | Sciact - CRIS-система Института катализа

Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond Научная публикация

Журнал

ChemPhysChem
ISSN: 1439-4235 , E-ISSN: 1439-7641

Вых. Данные

Год: 2021, Том: 22, Номер: 8, Страницы: 710-715 Страниц : 6 DOI: 10.1002/cphc.202001031

Ключевые слова

NMR signal enhancement; heterogeneous hydrogenation; immobilized metal complexes; parahydrogen-induced hyperpolarization; supported metal catalysts

Авторы

Chekmenev Eduard Y. ^1,2 , Goodson Boyd M. ³ , Bukhtiyarov Valerii I. ⁴ , Koptyug Igor V. ⁵

Организации

1	Department of Chemistry, Integrative Biosciences (Ibio) Wayne State University, Karmanos Cancer Institute (KCI), Detroit, MI 48202, USA
2	Russian Academy of Sciences, 14 Leninskiy prospect, Moscow 119991, Russia
3	Southern Illinois University, Department of Chemistry and Biochemistry, Materials Technology Center, Carbondale, IL 62901, USA
4	Boreskov Institute of Catalysis, SB RAS, 5 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
5	International Tomography Center, SB RAS, 3A Institutskaya st., Novosibirsk 630090, Russia

Информация о финансировании (10)

1	National Institutes of Health	1R21CA220137
2	National Institutes of Health	1R21HL154032-01
3	National Science Foundation	CHE-1904780
4	National Science Foundation	CHE-1905341
5	Российский фонд фундаментальных исследований	19-29-10003 (АААА-А19-119100890052-8)
6	United States Department of Defense	W81XWH-15-1-0271
7	United States Department of Defense	W81XWH-15-1-0272
8	United States Department of Defense	W81XWH-20-1-0576
9	United States Department of Defense	W81XWH-20-1-0578
10	National Institute of Biomedical Imaging and Bioengineering	1R01EB029829

Demonstration of parahydrogen‐induced polarization effects in hydrogenations catalyzed by heterogeneous catalysts instead of metal complexes in a homogeneous solution has opened an entirely new dimension for parahydrogen‐based research, demonstrating its applicability not only for the production of catalyst‐free hyperpolarized liquids and gases and long‐lived non‐equilibrium spin states for potential biomedical applications, but also for addressing challenges of modern fundamental and industrial catalysis including advanced mechanistic studies of catalytic reactions and operando NMR and MRI of reactors. This essay summarizes the progress achieved in this field by highlighting the research contributed to it by our colleague and friend Kirill V. Kovtunov whose scientific career ended unexpectedly and tragically at the age of 37. His role in this research was certainly crucial, further enhanced by a vast network of his contacts and collaborations at the national and international level.

Chekmenev E.Y. , Goodson B.M. , Bukhtiyarov V.I. , Koptyug I.V.
Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond
ChemPhysChem. 2021. V.22. N8. P.710-715. DOI: 10.1002/cphc.202001031 WOS Scopus РИНЦ CAPlus PMID OpenAlex

Поступила в редакцию:	20 дек. 2020 г.
Принята к публикации:	19 февр. 2021 г.
Опубликована online:	6 апр. 2021 г.
Опубликована в печати:	19 апр. 2021 г.

Web of science:	WOS:000637247300001
Scopus:	2-s2.0-85103907594
РИНЦ:	46831740
Chemical Abstracts:	2021:825775
PMID (PubMed):	33825286
OpenAlex:	W3139853929

БД	Цитирований
Scopus	4
Web of science	4
РИНЦ	1
OpenAlex	5