Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond | Sciact - CRIS-system of Boreskov Institute of Catalysis

Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond Full article

Journal

ChemPhysChem
ISSN: 1439-4235 , E-ISSN: 1439-7641

Output data

Year: 2021, Volume: 22, Number: 8, Pages: 710-715 Pages count : 6 DOI: 10.1002/cphc.202001031

Tags

NMR signal enhancement; heterogeneous hydrogenation; immobilized metal complexes; parahydrogen-induced hyperpolarization; supported metal catalysts

Authors

Chekmenev Eduard Y. ^1,2 , Goodson Boyd M. ³ , Bukhtiyarov Valerii I. ⁴ , Koptyug Igor V. ⁵

Affiliations

1	Department of Chemistry, Integrative Biosciences (Ibio) Wayne State University, Karmanos Cancer Institute (KCI), Detroit, MI 48202, USA
2	Russian Academy of Sciences, 14 Leninskiy prospect, Moscow 119991, Russia
3	Southern Illinois University, Department of Chemistry and Biochemistry, Materials Technology Center, Carbondale, IL 62901, USA
4	Boreskov Institute of Catalysis, SB RAS, 5 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
5	International Tomography Center, SB RAS, 3A Institutskaya st., Novosibirsk 630090, Russia

Funding (10)

1	National Institutes of Health	1R21CA220137
2	National Institutes of Health	1R21HL154032-01
3	National Science Foundation	CHE-1904780
4	National Science Foundation	CHE-1905341
5	Russian Foundation for Basic Research	19-29-10003 (АААА-А19-119100890052-8)
6	United States Department of Defense	W81XWH-15-1-0271
7	United States Department of Defense	W81XWH-15-1-0272
8	United States Department of Defense	W81XWH-20-1-0576
9	United States Department of Defense	W81XWH-20-1-0578
10	National Institute of Biomedical Imaging and Bioengineering	1R01EB029829

Demonstration of parahydrogen‐induced polarization effects in hydrogenations catalyzed by heterogeneous catalysts instead of metal complexes in a homogeneous solution has opened an entirely new dimension for parahydrogen‐based research, demonstrating its applicability not only for the production of catalyst‐free hyperpolarized liquids and gases and long‐lived non‐equilibrium spin states for potential biomedical applications, but also for addressing challenges of modern fundamental and industrial catalysis including advanced mechanistic studies of catalytic reactions and operando NMR and MRI of reactors. This essay summarizes the progress achieved in this field by highlighting the research contributed to it by our colleague and friend Kirill V. Kovtunov whose scientific career ended unexpectedly and tragically at the age of 37. His role in this research was certainly crucial, further enhanced by a vast network of his contacts and collaborations at the national and international level.

Chekmenev E.Y. , Goodson B.M. , Bukhtiyarov V.I. , Koptyug I.V.
Bridging the Gap: From Homogeneous to Heterogeneous Parahydrogen‐induced Hyperpolarization and Beyond
ChemPhysChem. 2021. V.22. N8. P.710-715. DOI: 10.1002/cphc.202001031 WOS Scopus РИНЦ AN PMID OpenAlex

Submitted:	Dec 20, 2020
Accepted:	Feb 19, 2021
Published online:	Apr 6, 2021
Published print:	Apr 19, 2021

Web of science:	WOS:000637247300001
Scopus:	2-s2.0-85103907594
Elibrary:	46831740
Chemical Abstracts:	2021:825775
PMID:	33825286
OpenAlex:	W3139853929

DB	Citing
Scopus	4
Web of science	4
Elibrary	2
OpenAlex	5