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Unraveling the Mechanism of Methane Activation on Zn‐Modified Zeolites by Solid‐State NMR Научная публикация

Журнал Chemistry-Methods
, E-ISSN: 2628-9725
Вых. Данные Год: 2021, Том: 1, Номер: 5, Страницы: 224-230 Страниц : 7 DOI: 10.1002/cmtd.202100021
Ключевые слова heterogeneous catalysis · methane activation · in situ NMR spectroscopy · solid-state NMR · Zn-modified zeolites
Авторы Stepanov Alexander G. 1,2 , Arzumanov Sergei S. 1 , Gabrienko Anton A. 1
Организации
1 Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)
2 Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090 (Russia)

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) 0239-2021-0003

Реферат: Methane activation on metal-containing zeolites is a hot topic because of the great potential of the application of these catalysts for the direct transformation of methane to methanol and aromatics under mild conditions. Solid-state nuclear magnetic resonance (SS NMR) spectroscopy is a powerful technique for characterizing small alkane activation and transformation on heterogeneous catalysts. It can provide insights into the different steps of alkane molecule activation that are difficult to assess with alternative methods. In this Concept article, the recent advances in the investigations of methane activation on Zn-modified zeolites performed with SS NMR are discussed. These studies demonstrate the breadth of information that can be obtained by SS NMR spectroscopy, such as the intermediates formed, the particular Zn species involved, the possible pathways of the alkane activation. The knowledge acquired with SS NMR provides the basis for the realization of the detected conversions of methane in practice.
Библиографическая ссылка: Stepanov A.G. , Arzumanov S.S. , Gabrienko A.A.
Unraveling the Mechanism of Methane Activation on Zn‐Modified Zeolites by Solid‐State NMR
Chemistry-Methods. 2021. V.1. N5. P.224-230. DOI: 10.1002/cmtd.202100021 РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 3 мар. 2021 г.
Опубликована в печати: 3 мая 2021 г.
Опубликована online: 3 мая 2021 г.
Идентификаторы БД:
РИНЦ: 47595695
Chemical Abstracts: 2022:2311535
Chemical Abstracts (print): 180:118390
OpenAlex: W3157490304
Цитирование в БД:
БД Цитирований
РИНЦ 9
OpenAlex 9
Альметрики: