Unraveling the Mechanism of Methane Activation on Zn‐Modified Zeolites by Solid‐State NMR Full article
| Journal |
Chemistry-Methods
, E-ISSN: 2628-9725 |
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| Output data | Year: 2021, Volume: 1, Number: 5, Pages: 224-230 Pages count : 7 DOI: 10.1002/cmtd.202100021 | ||||
| Tags | heterogeneous catalysis · methane activation · in situ NMR spectroscopy · solid-state NMR · Zn-modified zeolites | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
Abstract:
Methane activation on metal-containing zeolites is a hot topic because of the great potential of the application of these
catalysts for the direct transformation of methane to methanol and aromatics under mild conditions. Solid-state nuclear magnetic resonance (SS NMR) spectroscopy is a powerful technique for characterizing small alkane activation and transformation on heterogeneous catalysts. It can provide insights into the different steps of alkane molecule activation that are difficult to assess with alternative methods. In this Concept article, the recent advances in the investigations of methane activation on Zn-modified zeolites performed with SS NMR are discussed. These studies demonstrate the breadth of information that can be obtained by SS NMR spectroscopy, such as the intermediates formed, the particular Zn species involved, the possible pathways of the alkane activation. The knowledge
acquired with SS NMR provides the basis for the realization of the detected conversions of methane in practice.
Cite:
Stepanov A.G.
, Arzumanov S.S.
, Gabrienko A.A.
Unraveling the Mechanism of Methane Activation on Zn‐Modified Zeolites by Solid‐State NMR
Chemistry-Methods. 2021. V.1. N5. P.224-230. DOI: 10.1002/cmtd.202100021 РИНЦ ANCAN OpenAlex
Unraveling the Mechanism of Methane Activation on Zn‐Modified Zeolites by Solid‐State NMR
Chemistry-Methods. 2021. V.1. N5. P.224-230. DOI: 10.1002/cmtd.202100021 РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 3, 2021 |
| Published print: | May 3, 2021 |
| Published online: | May 3, 2021 |
Identifiers:
| Elibrary: | 47595695 |
| Chemical Abstracts: | 2022:2311535 |
| Chemical Abstracts (print): | 180:118390 |
| OpenAlex: | W3157490304 |