A Comprehensive Analysis of Kinetic Models for Methane Autothermal Reforming Reactions | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Comprehensive Analysis of Kinetic Models for Methane Autothermal Reforming Reactions Review

Journal

Fuel
ISSN: 0016-2361 , E-ISSN: 1873-7153

Output data

Year: 2025, Volume: 386, Article number : 134136, Pages count : 29 DOI: 10.1016/j.fuel.2024.134136

Tags

Hydrogen production; Methane autothermal reforming; Kinetic modeling; Methane steam reforming; Methane partial oxidation; Methane dry reforming

Authors

Jurado Javier ¹ , Trejo Fernando ¹ , Ancheyta Jorge ^2,3 , Elyshev Andrey ³ , Zagoruiko Andrey ⁴

Affiliations

1	Instituto Politecnico Nacional, Centro de Investigacion´ en Ciencia Aplicada y Tecnología Avanzada, Legaria 694, Col. Irrigacion, 11500 Mexico City, Mexico
2	E.S.I.Q.I.E., Instituto Polit´ecnico Nacional, UPALM, Zacatenco, Mexico City 07738, Mexico
3	Tyumen State University, Ulitsa Volodarskogo 6, Tyumen 625003, Russia
4	Boreskov Institute of Catalysis, Novosibirsk, Russia

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	FEWZ-2024-0015
2	National Council of Science and Technology

An analysis of the autothermal reforming (ATR) kinetic models reported in the literature was performed. The ATR model equations, kinetic parameters, experimental setup, and comparisons of experimental and simulated results were analyzed and discussed. The greatest part of the kinetic models accurately predicted the experimental data. The effect of the main operating variables on methane conversion and product selectivity are discussed. However, it is recognized that there is a need for a robust kinetic model of methane ATR, being the main challenge the accurate prediction of product yields and the temperature profile along the catalyst bed. The development of a new kinetic model needs to consider a balance between the number of kinetic parameters and the amount of experimental data, this latter is one of the main activities for further optimization of the methane ATR reactor technology.

Jurado J. , Trejo F. , Ancheyta J. , Elyshev A. , Zagoruiko A.
A Comprehensive Analysis of Kinetic Models for Methane Autothermal Reforming Reactions
Fuel. 2025. V.386. 134136 :1-29. DOI: 10.1016/j.fuel.2024.134136 WOS Scopus OpenAlex

Submitted:	Jul 25, 2024
Accepted:	Dec 16, 2024
Published online:	Jan 3, 2025
Published print:	Apr 15, 2025

Web of science:	WOS:001402172100001
Scopus:	2-s2.0-85213867656
OpenAlex:	W4406053617

DB	Citing
Scopus	3
OpenAlex	3
Web of science	2