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Hydrogen Production from Dimethyl Ether and Bioethanol for Fuel Cell Applications Full article

Conference 2nd World Congress of Young Scientists on Hydrogen Energy Systems
06-08 Jun 2007 , Turin
Journal International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487
Output data Year: 2008, Volume: 33, Number: 12, Pages: 3026-3030 Pages count : 5 DOI: 10.1016/j.ijhydene.2008.02.016
Tags Bioethanol steam reforming, Copper-cerium oxide, Dimethyl ether steam reforming, Nickel-cerium oxide, Preferential (selective) CO methanation, Rh/ZrO2
Authors Badmaev Sukhe D. 1 , Snytnikov Pavel V. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva, 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova St., 2 Novosibirsk, 630090, Russia

Funding (2)

1 Civilian Research and Development Foundation Y4-C-08-12
2 Global Energy Association

Abstract: Dimethyl ether (DME) and water–ethanol mixtures are promising and attractive sources of hydrogen for fuel cell applications. Copper-cerium oxide systems have been studied as the catalysts for DME steam reforming (SR) to hydrogen-rich gas mixtures. Hydrogen and carbon dioxide were the main reaction products; CO content was insignificant. For CO removal to 10 ppm, the level tolerated by low-temperature fuel cells in the hydrogen-rich feed gas—the reaction of preferential CO methanation in the presence of CO2 has been used. Nickel-cerium oxide system was used as the catalyst. SR of water–ethanol mixtures was performed using supported Rh catalyst. Reaction products of ethanol SR at 400 °C contained H2, CH4 and CO2. As the temperature increased to 600–700 °C, the CH4 concentration decreased considerably. The obtained hydrogen-rich gas mixture can be used as a feed for high-temperature solid-oxide fuel cells.
Cite: Badmaev S.D. , Snytnikov P.V.
Hydrogen Production from Dimethyl Ether and Bioethanol for Fuel Cell Applications
International Journal of Hydrogen Energy. 2008. V.33. N12. P.3026-3030. DOI: 10.1016/j.ijhydene.2008.02.016 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Aug 23, 2007
Accepted: Feb 7, 2008
Published online: Apr 18, 2008
Published print: Jun 1, 2008
Identifiers:
Web of science: WOS:000257532500025
Scopus: 2-s2.0-44749089471
Elibrary: 13591094
Chemical Abstracts: 2008:720441
Chemical Abstracts (print): 151:37374
OpenAlex: W2040215069
Citing:
DB Citing
Web of science 39
Scopus 46
Elibrary 47
OpenAlex 44
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