Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism Обзор
| Конференция |
11th European Workshop on Selective Oxidation - Selectivity in Oxidation - Key to New Resources Valorization (ISO) during the 12th European Congress on Catalysis - Balancing the Use of Fossil and Renewable Resources (Europacat) 30 авг. - 4 сент. 2015 , Kazan |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2016, Том: 278, Номер: Part 1, Страницы: 30-39 Страниц : 10 DOI: 10.1016/j.cattod.2016.04.033 | ||||
| Ключевые слова | Asymmetric catalysis, Enantioselective, Epoxidation, Hydrogen peroxide, Manganese, Mechanism | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский научный фонд | 14-13-00158 |
Реферат:
This mini-review summarizes the progress in the asymmetric epoxidation of olefins in the presence of manganese aminopyridine complexes, achieved in the last decade. The major breakthroughs in catalyst design, that eventually led to the emergence of highly enantioselective (> 99% ee) and efficient (> 1000 TON) catalysts, are discussed. The mechanistic studies carried out in recent years are given particular attention.
Библиографическая ссылка:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ CAPlusCA OpenAlex
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 17 нояб. 2015 г. |
| Принята к публикации: | 25 апр. 2016 г. |
| Опубликована online: | 12 мая 2016 г. |
| Опубликована в печати: | 1 дек. 2016 г. |
Идентификаторы БД:
| Web of science: | WOS:000388053000004 |
| Scopus: | 2-s2.0-84992736484 |
| РИНЦ: | 28170041 |
| Chemical Abstracts: | 2016:748637 |
| Chemical Abstracts (print): | 165:499763 |
| OpenAlex: | W2364384387 |