Partial Oxidation of Methane to Synthesis Gas on Pt Electrode in a Solid Oxide Electrolyte Cell
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736
, E-ISSN: 1588-2837
|
| Вых. Данные |
Год: 1996,
Том: 58,
Номер: 2,
Страницы: 407-416
Страниц
: 10
DOI:
10.1007/BF02067052
|
| Ключевые слова |
Methane, Partial oxidation, Platinum electrode-catalyst, Solid oxide electrolyte cell, Synthesis gas |
| Авторы |
Galvita V.V.
1
,
Belyaev V.D.
1
,
Sobyanin V.A.
1
|
| Организации |
| 1 |
Federal Scientific Center, Boreskov Institute of Catalysis,
Novosibirsk, 630090, Russia
|
|
Информация о финансировании (2)
|
1
|
International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union
|
94-3056
|
|
2
|
Российский фонд фундаментальных исследований
|
93-03-05097
|
The partial oxidation of methane to synthesis gas or oxyreforming of methane over a Pt electrode in a solid oxide electrolyte cell CH4+O2,Pt | ZrO2 (10mol%Y2O3)|Pt,air
has been studied under open and closed circuit conditions. Experiments were performed at atmospheric pressure over a temperature range of 700–800°C and methane/oxygen ratios of 0.4–1.8. The Pt electrode was found to be an active electrode-catalyst for oxyreforming of methane and electrochemical oxidation of the oxyreforming products. The mechanism of methane oxyreforming and the effect of anodic current passing through the cell on the catalytic properties of the Pt electrode for oxyreforming of methane are discussed.