Role of Free Radicals in Heterogeneous Complete Oxidation of Organic Compounds over IV Period Transition Metal Oxides Научная публикация
Конференция |
New Frontiers in Catalysis : 10th International Congress on Catalysis 19-24 июл. 1992 , Budapest |
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Сборник | New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992 Сборник, Elsevier. Amsterdam-London-New York-Tokyo.1993. 2859 c. |
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Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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Вых. Данные | Год: 1993, Том: 75, Страницы: 231-238 Страниц : 12 DOI: 10.1016/S0167-2991(08)64013-6 | ||
Авторы |
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Организации |
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Реферат:
Using the matrix isolation ESR technique the kinetic dependences of generation of RO2° radicals formed during n-alcohol and oxygen interaction over IV period transition metal oxides (TiO2, V2O5, Cr2O3, MnO2, Fe2O3, Co3O4, NiO, CuO, ZnO) were studied at low reagent pressures (Ptotal < 14 Pa) over the temperature range of 653 to 823 K. On the example of the oxidation reaction over CuCr2O4/γ–Al2O3 at atmospheric pressure the dependences of radical formation under conditions when secondary radical reactions may develop were investigated. Radical formation on the surfaces is believed to proceed via the common mechanism for all catalysts of the examined series, the chemisorbed surface oxygen species being involved in radical formation.
Библиографическая ссылка:
Ismagilov Z.R.
, Pak S.N.
, Krishtopa L.G.
, Yermolaev V.K.
Role of Free Radicals in Heterogeneous Complete Oxidation of Organic Compounds over IV Period Transition Metal Oxides
В сборнике New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.231-238. DOI: 10.1016/S0167-2991(08)64013-6 WOS WOS Scopus РИНЦ
Role of Free Radicals in Heterogeneous Complete Oxidation of Organic Compounds over IV Period Transition Metal Oxides
В сборнике New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, 19-24 July 1992. – Elsevier., 1993. – Т.1-3. – C.231-238. DOI: 10.1016/S0167-2991(08)64013-6 WOS WOS Scopus РИНЦ
Даты:
Опубликована в печати: | 1 янв. 1993 г. |
Опубликована online: | 29 мая 2008 г. |
Идентификаторы БД:
Web of science | WOS:A1993MH87500011 , WOS:A1993BZ34Y00011 |
Scopus | 2-s2.0-0041758785 |
РИНЦ | 28987992 |
Chemical Abstracts | 1993:649402 |
Chemical Abstracts (print) | 119:249402 |
OpenAlex | W20610733 |