Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition Научная публикация
Журнал |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Вых. Данные | Год: 2005, Том: 33, Номер: 3, Страницы: 243-246 Страниц : 4 DOI: 10.1016/j.supflu.2004.08.001 | ||||
Ключевые слова | Chemical reaction, Decomposition, Pressure effect, Supercritical water | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Международный научно-технический центр | 2383 |
Реферат:
It was shown experimentally that the rate of aliphatic nitrocompounds decomposition in supercritical water (SCW) depends on pressure/density at constant temperature. The SCW density dependence of the apparent rate constant of decomposition for each of three compounds under consideration (nitromethane, nitroethane and 1-nitropropane) was found to correlate with the density dependence of the H3O+ concentration in dissociated SCW. The rate constant of RNO2 decomposition in SCW decreased with increasing the length of hydrocarbon radical R.
Библиографическая ссылка:
Anikeev V.I.
, Yermakova A.
, Semikolenov V.A.
, Goto M.
Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition
The Journal of Supercritical Fluids. 2005. V.33. N3. P.243-246. DOI: 10.1016/j.supflu.2004.08.001 WOS Scopus РИНЦ
Effect of Supercritical Water Density on the Rate Constant of Aliphatic Nitrocompounds Decomposition
The Journal of Supercritical Fluids. 2005. V.33. N3. P.243-246. DOI: 10.1016/j.supflu.2004.08.001 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 28 июл. 2004 г. |
Принята к публикации: | 2 авг. 2004 г. |
Опубликована online: | 2 окт. 2004 г. |
Опубликована в печати: | 1 мар. 2005 г. |
Идентификаторы БД:
Web of science | WOS:000227412400005 |
Scopus | 2-s2.0-11144326754 |
РИНЦ | 13473676 |
Chemical Abstracts | 2004:1125115 |
Chemical Abstracts (print) | 142:340963 |
OpenAlex | W1986080001 |