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Formation of Anodic Layers on InAs (111)III. Study of the Chemical Composition Full article

Journal Semiconductors
ISSN: 1063-7826 , E-ISSN: 1090-6479
Output data Year: 2012, Volume: 46, Number: 4, Pages: 552-558 Pages count : 7 DOI: 10.1134/S1063782612040239
Tags Arsenic; Fluorine; Etching Time; Acid Electrolyte; Alkaline Electrolyte
Authors Valisheva N.A. 1 , Tereshchenko O.E. 1,3 , Prosvirin I.P. 2 , Kalinkin A.V. 2 , Goljashov V.A. 3 , Levtzova T.A. 1 , Bukhtiyarov V.I. 2
Affiliations
1 Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3 Novosibirsk State University, Novosibirsk, 630090 Russia

Funding (1)

1 Siberian Branch of the Russian Academy of Sciences 99

Abstract: The chemical composition of ∼20-nm-thick anodic layers grown on InAs (111)III in alkaline and acid electrolytes containing or not containing NH4F is studied by X-ray photoelectron spectroscopy. It is shown that the composition of fluorinated layers is controlled by the relation between the concentrations of fluorine and hydroxide ions in the electrolyte and by diffusion processes in the growing layer. Fluorine accumulates at the (anodic layer)/InAs interface. Oxidation of InAs in an acid electrolyte with a low oxygen content and a high NH4F content brings about the formation of anodic layers with a high content of fluorine and elemental arsenic and the formation of an oxygen-free InF x /InAs interface. Fluorinated layers grown in an alkaline electrolyte with a high content of O2− and/or OH− groups contain approximately three times less fluorine and consist of indium and arsenic oxyfluorides. No distinction between the compositions of the layers grown in both types of fluorine-free electrolytes is established.
Cite: Valisheva N.A. , Tereshchenko O.E. , Prosvirin I.P. , Kalinkin A.V. , Goljashov V.A. , Levtzova T.A. , Bukhtiyarov V.I.
Formation of Anodic Layers on InAs (111)III. Study of the Chemical Composition
Semiconductors. 2012. V.46. N4. P.552-558. DOI: 10.1134/S1063782612040239 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Валишева Н.А. , Терещенко О.Е. , Просвирин И.П. , Калинкин А.В. , Голяшов В.А. , Левцова Т.А. , Бухтияров В.И.
Формирование анодных слоёв на InAs(111). III. Исследование химического состава.
Физика и техника полупроводников. 2012. Т.46. №4. С.569-575. РИНЦ
Dates:
Submitted: Aug 25, 2011
Accepted: Oct 3, 2011
Published print: Apr 1, 2012
Published online: Apr 18, 2012
Identifiers:
Web of science: WOS:000303054200024
Scopus: 2-s2.0-84859837382
Elibrary: 17982973
Chemical Abstracts: 2012:562893
Chemical Abstracts (print): 156:652487
OpenAlex: W2060238215
Citing:
DB Citing
Web of science 7
Scopus 8
Elibrary 8
OpenAlex 9
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